Sv30140 synonyms component of hystemhystemchystemhp hydrogel kits recommended use in vitro methods 2. Exposure controlspersonal protection exposure guidelines. Based on the available data, the agency has concluded that triethylene glycol exhibits low toxicity and exposures to triethylene glycol used as both an active or inert ingredient do not present risks of concern to the agency. Recommended use of the chemical and restrictions on use. It appears that formaldehyde methylene glycol used in hair smoothing products must be in these products at levels higher than 0. Recall that one msds included methylene glycol at 5%. Methylene glycol and formaldehyde in living organisms. The level of exposure depends upon the dose, duration, and work being done. Firstaid measures description of first aid measures. Engineering and operating guide for dowtherm sr1 and.
For additional information about dowfrost propylene glycol based fluids, call 18004474369 and request form no. Product study of the oh radical and cl atom initiated oxidation of 1,3dioxane. The single oral lethal dose for humans has been estimated at 1. Material safety data sheet ethylene glycol monoethyl ether 6 other. In cases where several ounces 60 100 ml have been ingested, consider the use of ethanol and hemodialysis in the treatment.
Ethylene glycol is oxidized by alcohol dehydrogenase in the presence of nad to glycoaldehyde, which is then rapidly oxidized to glycolate. Name of substance diethylene glycol identifiers cas no 111466 molecular formula c4h10o3 molar mass 106. Flush the contaminated skin with water for at least 10 minutes. With emplura we offer a range of solvents for a plurality of basic applications in nonregulated industries and for less demanding applications, preparative laboratory work and cleaning purposes. High proof whisky can be administered prior to hospitalisation if treatment is delayed. Ethylene glycol abarrraarra aaaarabr a gggeegg ethylene oxide uuxrrruauua xcuuuuu r gggeeu formaldehyde 100% baaucaaa aaccbbu caaaa. Search results for methylene glycol at sigmaaldrich. No warranty, express or implied, is made and labchem inc. It appears that formaldehydemethylene glycol used in.
Ethylene glycol is widely used to inhibit the formation of natural gas clathrates hydrates in long multiphase pipelines that convey natural gas from remote gas fields to a gas processing facility. If released to the atmosphere, methylene blue will exist as both vapor and particulate in the ambient atmosphere. Safety data sheet mono ethylene glycol 1 identification of the substancepreparation and companyundertaking application automotive industry. Residues of triethylene glycol are exempted from the requirement of a tolerance when used as a deactivator in accordance with good agricultural practice as inert or. Ethylene carbonate sometimes abbreviated ec is the organic compound with the formula ch 2 o 2 co. Material safety data sheet msds mono ethylene glycol. Ethylene glycol 107211 60 ethylene glycol 107211 95 100 section 4. Haemodialysis is the most effective means of removing ethylene glycol and its metabolites form the body. It can harm the eyes, skin, kidneys, and respiratory system. Safety data sheet creation date 02feb2010 revision date 17jan2018 revision number 4 1. Evacuate all unauthorized personnel not participating in. Skin contact wash off immediately with plenty of water for at least 15 minutes. Safety data sheet according to 19072006ec, article 31.
June 4, 2014 the dow chemical company page 5 of 5 references 1 triethylene glycol, the dow chemical company, form no. Ethylene glycol is produced from ethylene ethene, via the intermediate ethylene oxide. Identification of the substancemixture and of the company undertaking. None information in this msds is from available published sources and is believed to be accurate. Methylene glycol is an ingredient used in some hairstraightening products. Ethylene glycol can be recovered from the natural gas and reused as an inhibitor after purification treatment that removes water and inorganic salts. First aid measures general advice consult a physician. Ethylene glycol material safety data sheet cas no 107211. Additional first aid remarks treatment is required within the first three hours of exposure. Ethylene glycol monomethyl ether is incompatible with oxygen and strong oxidizing agents. Amended safety assessment of formaldehyde and methylene glycol as used in cosmetics.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Formaldehyde is a toxic substance, and since the reaction with water is reversible, products containing methylene glycol can, under some circumstances, release formalde hyde. Final amended report formaldehyde and methylene glycol. Chemical product and company identification product name. Methylene glycol in hair straighteners european commission. On that basis, treatment similar to ethylene glycol intoxication may be of benefit. Msds mono ethylene glycol page 1 of 8 material safety data. Ethylene glycol ec50 96 h 6500 00 mgl not listed ec50 0 mgl 16 h ec50 620 mgl 30 min ec50 620. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Methylene glycol is continuously converted to formaldehyde, and vice versa, even at equilibrium, which can be easily shifted by heating, drying, and other conditions to increase the amount of. Ethylene oxide reacts with water to produce ethylene glycol according to the chemical equation. Identification product name ethylene glycol monomethyl ether certified cat no. Ethylene glycol monomethyl ether certified revision date 17jan2018 eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. It is formed by the reac tion of formaldehyde with water.
Material safety data sheet ethylene glycol msds section 1. Ethylene glycol base ethylene glycol has produced birth defects in rodents. According to a classification scheme, this bcf value suggests that bioconcentration in aquatic organisms. They argued that the exposure measurements they provided show very low exposures to formaldehyde in use situations. Ethylene dichloride msds pdf liquid ammonia and ethylene dichloride can cause an explosion when mixed, nfpa m, a tank of dimethyl amino propyl amine exploded. Your best source for triethylene glycol quality dow is the worlds largest producer of. If not breathing give artificial respiration consult a physician. Immediately flush eyes with plenty of water for at least 10 minutes. Opinion of the scientific committee on consumer safety on. Methylene glycol is therefore considered the hydrated form of formaldehyde and serves as a reservoir of formaldehyde in water because the dehydration of methylene glycol is rapidly reversible under a variety of conditions. Product and company identification product name poly ethylene glycol diacrylate, pegda for hystem kits cat no. Chemical product and company identification product id. Ethylene glycol monoethyl ether 7 section 16 other information msds creation date.
The agency has determined triethylene glycol is eligible for reregistration. Methylene glycol exists in equilibrium with fa which is produced as a metabolic byproduct as part of one carbon metabolism. Ethylene glycol 107211 mono ethylene glycol alcohol resistant foam. If inhaled if breathed in, move person into fresh air. Safety data sheet polyethylene glycol 400 version 1. Methylene chloride is metabolically converted to carbon monoxide after systemic absorption, which yields increased concentrations of carboxyhemoglobin in the blood. Never give anything by mouth to an unconscious person. Vaporphase methylene blue is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals with an estimated halflife of about 1. Diethylene glycol cas no 111466 material safety data sheet sdsmsds section 1. Possibility of hazardous reactions not established. Hazards identification target organs eyes, skin potential health effects acute. Dissolved in water, a molecule of formaldehyde which is a gas at room temperature reacts with a molecule of water to form methylene glycol. Triethylene glycol is produced, as an intermediate or final product, by process units covered under this subpart. Ethylene glycol poisoning will always cause metabolic acidosis.
Show this safety data sheet to the doctor in attendance. Show this material safety data sheet to the doctor in attendance. Store in cool, dry place in tightly closed containers. Triethylene glycol 97 112276 2039532 c 6 h 14 o 4 150. This guide provides information about dowtherm ethylene glycol based fluids only. Central drug house p ltd 728 vardaan house new delhi2. Before considering the potential toxicity of mg its ubiquitous presence in all living systems is first addressed. Workers may be harmed from exposure to ethylene glycol. If ethanol is used, a therapeutically effective blood. Emplura is our lowcost alternative to highpurity qualities. If unconscious place in recovery position and seek medical advice. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa. Identification product name ethylene glycol cat no.
Identification of the substancemixture and of the companyundertaking 1. Material safety data sheet nr02460 propylene glycol 1. Consult standard literature for details of treatment. Ethylene glycol is more acutely toxic for humans than for laboratory animals by ingestion. At room temperature 25 c ethylene carbonate is a transparent crystalline solid, practically odorless and colorless, and somewhat soluble in water. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Ethylene glycol material safety data sheet cas no 107. What was not received from the pksc were the levels of methylene glycol in hair smoothing products.
Triethylene glycol compatibility with elastomeric materials properties. Safety data sheet creation date 11jun2014 revision date 17jan2018 revision number 4 1. First aid measures description of first aid measures firstaid measures general get medical adviceattention if you feel unwell. Incompatible with acid chlorides and acid anhydrides. Poly ethylene glycol blockpolylactone methyl ether, poly ethylene glycol methyl etherblockpolylactide 570281 plla average m n 5,000, peg average m n 5,000. Bioaccumulation accumulation no information available mobility.
Accidental release measures personal precautions, protective equipment and emergency procedures. Triethylene glycol 2,21,2ethanediylbisoxy 112276 100. Ethylene glycol please ensure that this msds is given to, and explained to people using this product. Ethylene glycol industrial ethylene glycol meglobal glycol solv ethylene glycol, section 4. Amended safety assessment of formaldehyde and methylene. Ethylene glycol stearate slightly soluble gum damar slightly soluble heptane slightly soluble hydrous wool fat slightly soluble kauri gum slightly soluble.
It is classified as the carbonate ester of ethylene glycol and carbonic acid. Do not handle until all safety precautions have been read and understood. Page 2 of 5 msds t mono ethylene glycol irritation. Early administration of ethanol may counter the effects of monoethylene glycol.